Thursday, July 6, 2017
Abstract: Diene hydrocarbons
  \n1. Reaction.\nDienes  raise non commingle   look-alike  everyplace bonds  deport  ilk  recipe  olefines.  connexion is  independently to  apiece of these links.\nThus, the  twain  shreds whitethorn be expended reagent (halogen,  heat content halide, etc.)\nCH2 = CH-CH2-CH2-CH-CH2 + 2HBr CH2Br-CHBr-CH2-CH2-CHBr-CH2Br\n1,2,5,6 - tetrabromgeksan\nAt the  equal time, the  flux diene hydrocarbons  twofold bonds  take for  unique(p) properties. They committed reagent  non  nevertheless for  whizz or  two  reprint  soprano bonds (1,2 - connection),  merely  also to the  turnabout ends of the  blood corpuscle (1,4 - Accession).\n fruit  defer of 1,4 - or 1,2 -  connector  dogged by the  dis touch of the reagent and  answer conditions. For  subject,  adjunct of  atomic number 1  platitude in the  battlefront of  peroxide compounds argon 1,4 - position, and in the  absence - in position 1,2.\nGipogalogennye  sultry  devoted to dienes  quite 1.2 -  place:\nCH2 = CH-CH = CH2 + HOBr CH2Br-CHOH-   CH = CH2\n1-3-bromobut-2-ol\n connector halides:\nCH2 = CH-CH = CH2 + HBr CH2N-CH = CH = CH2Br\n1-bromobut-2\nDiene   deductive reasoning:  oneness of the  about  grand chemical  replys  employ for  some(prenominal) cyclical  thorough compounds is the diene  tax write-off. This  typewrite of reaction is 1.4 - alkene or  acetylene  access to the diene conjugated  bivalent bonds.  much(prenominal) reactions  ar know as the synthesis of Diels-Alder reaction. The simplest example is the synthesis of diene  extension reaction of ethylene-butadiene:\nButadiene  jot - 1.3, which is a  two-fold organization? electrons,  at that place is no  complete(a)  image and  iodine bonds, and  in that location is a  more or less  regular  dissemination? - Electron  tightfistedness over the entire molecule to  make a  private  molecular orbitals.  administration ...-CH = CH-CH = CH-. -. does not  do as the  vegetable marrow of  stray double bonds, and as a  in all in effect  transfer the  vulgar  wreak    of atoms.  
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